Pribor (Cesko) – druhy vyskyt karbonatu vazanych na vyvery uhlovodiku spjaty s vylevnymi horninami tesinitove asociace

During the construction of the Příbor bypass road (2009–2011), a body of volcanic rocks belonging to the Teschenite Association (Fig. 2), enveloped by the Lower Cretaceous (upper Barremian) sediments, was uncovered on the western edge of the city. The rocks are unaltered to strongly altered picritic rocks near the thrust plane. Completely altered hyaloclastites, or hyaloclastite breccias, were also recognized. These rocks are smectitized (montmorillonite-saponite), carbonatized, and impregnated with pyrite and marcasite. Anatase, baryte, palygorskite, and quartz are accessory phases. The findings of xenocrysts of Cr-rich oxyspinelides as well as calcite pseudomorphs after olivine in the weathered zone provide evidence for the affiliation of hyaloclastites to picritic rocks. Further excavation work near the roundabout (Fig. 1, GPS coordinates N 49° 38.417’ E 018° 07.745’) in 2017 uncovered in these rocks blocks of carbonate material up to 15 × 15 × 25 cm in size. The carbonate material makes fillings of cavities in the hyaloclastite breccia. Their oldest mineral is pyrite that forms fibrous aggregates (sunflower microtexture) up to several centimeters long (Fig. 3) composed of pyrite framboids overgrown by tabular pyrite (Fig. 4). The pyrite aggregates are covered by an older generation of calcite resembling speleothems (stalactites) with a distinctly concentric structure. The spaces between the stalactites are filled by younger white coarse-grained crystalline calcite, in places within cavities (Fig. 3). The isotopically very light sulfur in pyrite with the sunflower microtexture (δ³⁴S -39.9 ‰ CDT) indicates its bacterial origin at anoxic conditions. The aggregates probably represent the original strings of chemotrophic bacteria colonies. Isotopic signature of six calcite samples (δ¹³C down to -45.6 ‰ V-PDB, δ¹⁸O 26.7–30.6 ‰ V-SMOW) demonstrates their cold (hydrocarbon) seep origin (Tab. 1, Fig. 5). These seeps were probably thermally induced by the ascending magma and its extrusion onto the seabed. A similar formation was previously documented for the carbonate from the Baška locality (δ¹³C up to -28.3 ‰ V-PDB), where it is bound to pillow lavas of the Teschenite Association Rocks. Worldwide, the thermogenic methane seeps triggered by active volcanism are known, but usually not associated with the formation of seep carbonates.

References

Aarnes, I. – Svensen, H. – Connolly, J. A. D. – Podladchikov, Y. Y. (2010): How contact metamorphism can trigger global climate changes: Modelling gas generation around igneous sills in sedimentary basins. – Geochim. Cosmochim. Ac. 74, 7179–7195.

Alfonso, P. – Prol-Ledesma, R. M. – Canet, C. – Melgarejo, J-C. – Fallick, A. E. (2005): Isotopic evidence for biogenic precipitation as a principal mineralization process in coastal gasohydrothermal vents, Punta Mita, Mexico. – Chem. Geol. 224 (1–3), 113–121.

Ascher, E. (1906): Die Gastropoden, Bivalven und Brachiopo- den der Grödischter Schichten. In: Uhlig, V. – Diener, C. – von Arthaber, C., ed.: Beiträge zur Paläontologie und Geo- logie Österreich-Ungarns und des Orients, 135–172. – Mitt. Geol.-paläont. Inst. Univ. Wien 19.

Bojanowski, M. J. (2007): Oligocene cold-seep carbonates from the Carpathians and their inferred relation to gas hydrates. – Facies 53 (3), 347–360.

Bojanowski, M. J. – Oszczypko-Clowes, M. – Barski, M. – Oszczypko, N. – Radzikowska, M. – Ciesielska, Z. (2021): Slope destabilization provoked by dissociation of gas hydrates in the Outer Carpathian basin during the Oligocene: Sedimentological, petrographic, isotopic and biostratigraphic record. – Mar. Petrol. Geol. 123, 104585.

Brunarska, I. – Anckiewicz, R. (2019): Geochronology and Sr–Nd–Hf isotope constraints on the petrogenesis of teschenites from the type-locality in the Outer Western Carpathians. – Geol. Carpath. 70 (3), 222–240.

Buriánek, Z. – Dolníček, Z. (2001): Nález karbonátové horniny v lomu u Omic (brněnský masiv). – Geol. Výzk. Mor. Slez. 8, 77–78.

Campbell, K.A. (2006): Hydrocarbon seep and hydrothermal vent paleoenvironments and paleontology: Past developments and future research directions. – Palaeogeogr. Palaeocl. 232, 362–407.

Cochran, J. K. – Landman, N. H. – Jakubowicz, M. – Brezina, J. – Naujokaityte, J. – Rashkova, A. – Garb, M. P. – Larson, N. L. (2022): Geochemistry of cold hydrocarbon seeps: an overview. In: Kaim, A. – Cochran, J. K. – Landman, N. H., ed.: Ancient hydrocarbon seeps, 3–45. – Topics Geobiol. 53.

Danišík, M. – Pánek, T. – Matýsek, D. – Dunkl, I. – Frisch, W. (2008): Apatite fission track and (U-Th)/He dating of teschenite intrusions gives time constraints on accretionary processes and development of planation surfaces in the Outer Western Carpathians. – Z. Geomorph. N. F. 52 (3), 273–289.

Degens, E. T. (1967): Chapter 5: Stable isotope distribution in carbonates. In: Chilingar G. V. – Bissell, H. J. – Fairbridge, R. W., ed.: Developments in sedimentology, vol. 9, part B, 193–208. – Elsevier. Amsterdam

Dolníček, Z. – Lehotský, T. – Slobodník, M. – Hejtmánko- vá, E. – Grígelová, A. – Zapletal, J. (2005): Mineral-for- ming and diagenetic processes related to Tertiary hydrocarbon seepage at the Bohemian Massif/Outer Western Carpathians interface: Evidence from the Hrabůvka quarry, Moravia, Czech Republic. – Mar. Petrol. Geol. 12, 77–92.

Dolníček, Z. – Malý, K. (2005): Izotopově anomální sedi - mentární karbonátová hornina z Domašova n. Bystřicí (kulm Nízkého Jeseníku). – Geol. Výzk. Mor. Slez v Roce 2004, 12, 49–51.

Dolníček, Z. – Slobodník, M. (2008): Nový nález mineralizace s uhlovodíky v lomu cementárny v Hranicích. In: Krmíček, L. – Halavínová, M. – Šešulka, V., ed.: Moravskoslezské paleo- zoikum 2008: sbor. abstraktů, 5. – ÚGV PřF Masarykovy univ., Čes. geol. spol., Čes. geol. služba. Praha, Brno.

Dolníček, Z. – Urubek, T. – Kropáč, K. (2010): Post-magmatic hydrothermal mineralization associated with Cretaceous picrite (Outer Western Carpathians, Czech Republic): interaction between host rock and externally derived fluid. – Geol. carpath. 61 (4), 327–339.

Dostal, J. – Owen, J. V. (1998): Cretaceous alkaline lamprophyres from northeastern Czech Republic: geochemistry and petrogenesis. – Geol. Rundsch. 87 (1), 67–77.

Dubinina, E. O. – Chernyshev, I. V. – Bortnikov, N. S. – Lein, A. Yu. – Sagalevich, A. M. – Goľtsman, Yu. V. – Bairova, E. D. – Mokhov, A. V. (2007): Isotopic-geochemical characteristics of the Lost City hydrothermal field. – Geochem. Int. 45 (11), 1131–1143.

Eliáš, M. – Skupien, P. – Vašíček, Z. (2003): Návrh úpravy litostratigrafického členění nižší části slezské jednotky na českém území (vnější Západní Karpaty). – Sbor. věd. Prací Vys. Šk. báň., Ř. horn.-geol. 49 (8), 7–13.

Hail Hakimi, M. – Lashin, A. – Gharib, A. F. – Rahim, A. – Abdulmumini Yelwa, N. – Nasher, M. A. – Lotfy, N. M. – Afify, W. E. (2022): The effect of Pliocene volcanic intrusive rocks and thermogenic gas generation from the Miocene Salif Formation in the offshore Tihamah Basin, Yemeni Red Sea. – Mar. Petrol. Geol. 146, 105923.

Hladíková, J. – Šmejkal, V. – Šmíd, B. – Haur, A. (1972): The carbon and oxygen isotopes in calcites of the teschenite association and in the Tithonian and Berriasian limestones (Moravskoslezské Beskydy Mts.). – Věst. Ústř. Úst. geol. 47, 333–340.

Hohenegger, L. (1861): Geognostische Karte der Nord Karpa- then in Schlesien und den angrenzenden Theilen von Maehren und Galizien. – 1 list. Justus Perthes. Gotha.

Chan, C. S. – McAallister, S. – Leavitt, A. H. – Glazer, B. T. – Krepski, S. T. – Emerson, D. (2016): The architecture of iron microbial mats reflects the adaptation of chemo- lithotrophic iron oxidation in freshwater and marine environ- ments. – Front. Microbiol. 7, 1–18.

Chang, J. – Li, Y. – Lu, H. (2022): The morphological cha- racteristics of authigenic pyrite formed in marine sediments. – J. Mar. Sci. Eng. 10 (10), 1533.

Idrisova, E. – Gabitov, R. – Karamov, T. – Voropaev, A. – Liu, M.-C. – Bogdanovich, N. – Spasennykh, M. (2021): Pyrite morphology and ?34S as indicators of depositional environment in organic-rich shales. – Geosciences 11 (9), 355.

Jakubowicz, M. – Dopieralska, J. – Kaim, A. – Skupien, P. – Kiel, S. – Belka, Z. (2019): Nd isotope composition of seep carbonates: Towards a new approach for constraining subseafloor fluid circulation at hydrocarbon seeps. – Chem. Geol. 503, 40–51.

Jirásek, J. – Skupien, P. – Matýsek, D. (2013): Stroncianit z obchvatu města Příbor (Morava, Česká republika). – Acta Mus. Morav., Sci. geol. 98 (1), 49–57.

Kaim, A. – Skupien, P. – Jenkins, R. G. (2013): A new Lower Cretaceous hydrocarbon seep from the Czech Carpathians and its fauna. – Palaeogeogr. Palaeocl. 390, 42–51.

Klvaňa, J. (1897): Tešenity a pikrity na severovýchodní Mo- ravě. – Rozpr. Čes. Akad. Věd, Vědy, Slovesn. Umění, Tř. II, 6 (23), 1–93.

Kohn, M. J. – Riciputi, L. R. – Stakes, D. – Orange, D. L. (1998): Sulfur isotope variability in biogenic pyrite: Reflections of heterogeneous bacterial colonization? – Am. Mineral. 83 (11), 1454–1468.

Kropáč, K. – Dolníček, Z. – Uher, P. – Buriánek, D. – Sa- fai, A. – Urubek, T. (2020): Zirconian-niobian titanite and associated Zr-, Nb-, REE-rich accessory minerals: Products of hydrothermal overprint of leucocratic teschenites (Silesian Unit, Outer Western Carpathians, Czech Republic). – Geol. carpath. 71 (4), 343–360.

Krystek, I. – Samuel, O. (1978): Výskyt kriedy karpatského typu severne od Brna (Kuřim). – Geol. Práce, Spr. (Bratislava) 71, 93–110.

Kučerová-Charvátová, K. – Kučera, J. – Dolníček, Z. (2005): Chapter 2-17: Origin and significance of calcite-marcasite- pyrite mineralization in siliciclastic Lower Carboniferous rocks, eastern margin of the Bohemian Massif, Czech Republic. In: Mao, J. – Bierlein, F. P., ed.: Mineral deposit research: meeting the global challenge, vol. 1, 141–143. – Springer- Verlag. Berlin, Heidelberg.

Kynický, J. (2010): Minerály hydrotermálních žil v horninách těšínitové asociace v okolí Příbora. – Minerál, 18 (6), 484–494.

Lin, Q. – Wang, J. – Algeo, T. J. – Sun, F. – Lin, R. (2016): Enhanced framboidal pyrite formation related to anaerobic oxidation of methane in the sulfate-methane transition zone of the northern South China Sea. – Mar. Geol. 379, 100–108.

Loyd, S. J. – Sample, J. – Tripati, R. E. – Defliese, W. F. – Brooks, K. – Hovland, M. – Torres, M. – Marlow, J. – Hancock, L. G. – Martin, R. – Lyons, T. – Tripati, A. E. (2016) Methane seep carbonates yield clumped isotope signatures out of the equilibrium with formation temperatures. – Nat. Commun. 7, 12274

Lucińska-Anczkiewicz, A. – Villa, I. M. – Anczkiewicz, R. – Slaczka, A. (2002): ⁴⁰Ar/³⁹Ar dating of alkaline lamprophyres from the Polish Western Carpathians. – Geol. carpath. 53 (1), 45–52.

Matýsek, D. – Jirásek, J. (2016): Occurrences of slawsonite in rocks of the Teschenite Association in the Podbeskydí Piedmont area (Czech Republic) and their petrographical significance. – Can. Mineral. 54 (5), 1129–1146.

Matýsek, D. – Jirásek, J. – Skupien, P. – Thomson, S. N. (2018): The Žermanice sill: new insights into the mineralogy, petrology, age, and origin of the teschenite association rocks in the Western Carpathians, Czech Republic. – Int. J. Earth Sci. 107 (7), 2553–2574.

McCrea, J. M. (1950): On the isotopic chemistry of carbonates and a paleotemperature scale. – J. Chem. Phys. 18 (6), 849–857.

Menčík, E. – Adamová, M. – Dvořák, J. – Dudek, A. – Jetel, J. – Jurková, A. – Hanzlíková, E. – Houša, V. – Peslová, H. – Rybářová, L. – Šmíd, B. – Šebesta, J. – Tyráček, J. – Vašíček, Z. (1983): Geologie Moravskoslezských Beskyd a Podbeskydské pahorkatiny. – 307 str. Academia. Praha.

Merinero, R. – Cárdenes, V. (2018): Theoretical growth of framboidal and sunflower pyrite using the R-package framb- growth. – Mineral. Petrol. 112 (4), 577–589.

Merinero, R. – Lunar, R. – Somoza, L. – Díaz-del-Rio, V. – Martínez-Frías, J. (2009): Nucleation, growth and oxidation of framboidal pyrite associated with hydrocarbon-derived submarine chimneys: lessons leasrend from the Gulf of Cadiz. – Eur. J. Mineral. 21 (5), 947–961.

Pacák, O. (1926): Sopečné horniny na severním úpatí Bezkyd moravských. – 232 str. Čes. akad. věd a umění. Praha.

Paull, C. K, Hecker, B. – Freeman-Lynde, R. P. – Neumann, C. – Corso, W. P. – Golubic, S. – Golubic, S. – Hook, J. E. – Sikes, E. – Curray, J. (1984): Biological communities at the Florida Escarpment resemble hydrothermal vent taxa. – Science 226 (4677), 965–967.

Peckmann, J. – Thiel, V. (2004): Carbon cycling at ancient methane–seeps. – Chem. Geol. 205 (3), 443–467.

Peckmann, J. – Thiel, V. – Michaelis, W. – Clari, P. – Gaillard, C. – Martiere, L. – Reitner, J. (1999): Cold seep deposits of Beauvoisin (Oxfordian; southaestern France) and Marmorito (Miocene; northern Italy): microbially induced authigenic carbonates. – Int. J. Earth Sci. 88 (1), 60–75.

Picha, F. J. – Stráník, Z. – Krejčí, O. (2006): Geology and hydrocarbon resources of the Outer Western Carpathians and their foreland, Czech Republic. In: Golonka, J. – Picha, J., ed.: The Carpathians and their foreland: geology and hydro- carbon resources, 49–175. – AAPG Memoir 84. Tulsa.

Révész, K. – Qi, H. – Coplen, T.B. (2012): Determination of the ?34S of total sulfur in solids; RSIL lab code 1800, version 1.2. In: Révész, K. – Coplen, T. B., ed.: Methods of the Reston Stable Isotope Laboratory, 1–31. – U.S. Department of the Interior, U.S. Geological Survey.

Rickard, D. (2021): Framboids. – 320 str. Oxford University Press. Oxford.

Sandy, M. R. – Lazăr, I. – Peckmann, J. – Birgel, D. – Stoi- ca, M. – Roban, R. D. (2012): Methane-seep brachiopod fauna within turbidites of the Sinaia Formation, Eastern Carpathian Mountains, Romania. – Palaeogeogr. Palaeocl. 323-325, 42–59.

Scott, R. J. – Meffre, S. – Woodhead, J. – Gilbert, S. E. – Berry, R.F. – Emsbo, P. (2009): Development of framboidal pyrite during diagenesis, low-grade regional metamorphism, and hydrothermal alteration. – Econ. Geol. 104 (8), 1143–1168.

Skupien, P. – Pavluš, J. (2013): Příspěvek k poznání stratigrafické pozice magmatitů těšínitové asociace ve slezské jednotce. – Geol. Výzk. Mor. Slez. 20 (1–2), 96–99.

Suess, E. (2014): Marine cold seeps and their manifestations: geological control, biogeochemical criteria and environmental conditions. – Int. J. Earth Sci. 103 (7), 1889–1916.

Svensen, H. – Planke, S. – Malthe-Sorenssen, A. – Jamt- veit, B. – Myklebust, R. – Rasmussen Eidem, T. – Rey, S. S. (2004): Release of methane from a volcanic basin as a mechanism for initial Eocene global warming. – Nature 429, 542–545.

Szopa, K. – Włodyka, R. – Chew, D. (2014): LA-ICP-MS U-Pb apatite dating of Lower Cretaceous rocks from teschenite- picrite association in the Silesian Unit (southern Poland). – Geol. carpath. 65 (4), 273–284.

Šmíd, B. (1978): Výzkum vyvřelých hornin těšínitové asociace. – MS Čes. geol. služba. Praha.

Whiticar, M. J. – Suess, E. – Wehner, H. (1985): Thermogenic hydrocarbons in surface sediments of the Bransfield Strait, Antarctic Peninsula. – Nature 314, 87–90.

Włodyka, R. (2010): Ewolucja składu mineralnego skał cieszyńskiej prowincji magmowej. – 232 str. Wydawnictwo Uniwersytetu Śląskiego. Katowice.